sphere bohr model more electrons or fewer electrons than the neutral atom? --- periodic chart (92 different types of spheres) workhorses H, O, C, N P, S Na, K, Mg, Ca, Cl essential salts Fe, Mn, Zn, Co trace mineral Pb, Sn, Hg, U, Pu DO NOT WANT --- atoms combine to form molecules atoms stick together a few different ways + - spheres Na+ Cl- electrostatic H-H O=O N=N covalent Lewis electron dot, valence electrons, count to 8 or 18 --- H-O-H H HCH H tetrahedron four-sided, with each side an equil triangle CH3 -- stick figures 1 methane 2 ethane 3 propane 4 n-butane isobutane 5 pentane --- functional groups methanol ethanol 1-propanol, 2-propanol butanol formaldehyde acetaldehyde formic acid acetic acid propionic acid butyric acid --- acid + alcohol forms an ester ethyl acetate greasy biological stuff is all lumped together as "lipids" cholesterol, oils (liq), fats (solids) what we're interested in are those that combine a special triple-threat alcohol known as "glycerol" CH2OHCHOHCH2OH with a long chain organic acid known as a (wait for it) "fatty acid" CH3(CH2)nCOOH for n=14,16 condensation (bringing together, taking water out) hydrolysis (taking apart by putting water in) --- biodiesel is not the same thing as straight vegetable oil (SVO, WVO, PPO) glycerine + 3 fatty acids makes for a heavy molecule (>3X) solid at cold temperatures doesn't vaporize as easily doesn't burn as easily carbon deposits dual fuel heaters --- biodiesel take one molecule of fat, break it up into four molecules, one of glycerol and 3 of fatty acid where glycerol had been, hooking in a methanol (or ethanol) --- supercalifragilisticexpialidocious antidisestablishmentarianism transubstantiation transesterification ---